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21. Mariska Hargitay and Peter Hermann
Mariska Hargitay was 40 when she married Peter Hermann in 2004.

The two met on the set of Law and Order: Special Victims Unit back in November 2001. The two were casually discussing religion when Hermann suggested he come to church with her. "I just about passed out when I saw him there," Hargitay told InStyle. "I thought, that's my husband."